The elbow was welded with two straight pipes at two ends. Types 304, 304l and 304h are the most versatile and widely used of all the stainless steels. In general its resistance to pitting and crevice corrosion resistance is close to that of grade 304. Alloy 316316l is molybdenumbearing austenitic stainless steel. Duplex stainless steel has become more and more popular for its combination of strength and affordability.
It is subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above 60 c approximate. The material used in the present study is 304 stainless steel, the chemical composition of it is shown in table i. Laboratory tests were conducted to investigate the stress corrosion cracking scc of 304l stainless steel used to construct the containment vessels for the storage of plutoniumbearing materials. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. The reason why austenitic stainless steel is very prone to this kind of stress corrosion cracking is. Stress corrosion cracking of sensitized type 304 stainless. Member of asm international general corrosion resistance of custom 465 stainless approaches that of type 304 stainless.
Corrosion of stainless steels stainless steels coursera. Corrosion of unprotected carbon steel occurs even inside reinforced. Stress corrosion cracking of aisi 304 and aisi 316. Effects of marine environments on stress corrosion. Stress corrosion cracking scc of duplex stainless steel. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i. The stress corrosion cracking scc of a commercial austenitic stainless steel type 304 was investigated as functions of chloride concentration, chromate concentration and test temperature under a constant applied stress condition in 0. Stress corrosion cracking response of 304 stainless steel in. Threshold temperature for stress corrosion cracking of duplex. Type 304 has good processability, weldability, corrosion resistance, heat. Type 444 is equivalent to type 304 in many corrosion environments and has lower coefficient of expansion and better thermal conductivity. Stainless steel 304 has excellent corrosion resistance in a wide variety of environments and when in contact with different corrosive media.
In some instances type 304 can be used in the aswelded condition. Chloride stress corrosion cracking inspectioneering. Stress corrosion cracking scc is a common issue with many specialty alloys. Stress corrosion cracking resistance of grade 430 is very high, as it is for all ferritic grades. Studies published on stress corrosion cracking scc in sensitized type 304 stainless steel 304ss in thiosulphate solutions have focused on the effect of thiosulphate ion concentration on the crack growth rate,, possible mechanisms for the phenomenon,, initiation and propagation of cracks,, and the electrochemistry of the system. It is still sometimes referred to by its old name 188 which is derived from the nominal composition of type 304 being 18% chromium and 8% nickel. Transgranular stress corrosion cracking of 304l stainless. F kjkg it has superior chloride stress corrosion cracking resistance to types 304 and 316. The datasheet and specification are summarized in the following tables including. Chlorideinduced stress corrosion cracking of austenitic. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. The number of cracks increases with increasing potential, and the crack depth decreases with accelerated straining. So stress corrosion cracking is very important in austenitic stainless steel.
The presence of 23 wt% molybdenum in the alloy makes the passive film stronger kain et al. The effect of cold work on the stresscorrosion cracking. Type 304 has good processability, weldability, corrosion resistance, heat resistance, low. Low temperature stress corrosion cracking of stainless. Pitting and crevice corrosion can occur in environments containing chlorides.
Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Stress corrosion cracking can occur at temperatures over 60c. The effect of cold work on stress corrosion cracking of type 302 austenitic stainless steel wire exposed to boiling 154 c, 309 f 42 weightpercent aqueous magnesium chloride solution was determined. Scc will occur when stainless steels are subjected to tensile stress, while in contact with solutions containing chlorides. Effects of marine environments on stress corrosion cracking. Insitu monitoring of stress corrosion cracking of 304. Fatigue crack growth of aisi 304 stainless steel welds in. It is also referred to as 188 stainless steel, a2 stainless steel as per the iso 3506, or 304s15 as per the british standard.
The type 321 austenitic stainless steel is susceptible to stress corrosion cracking scc in halides similar to type 304 stainless steel. Effects of marine environments on stress corrosion cracking of austenitic stainless steels 1011820 effective december 6, 2006, this report has been made publicly available in accordance with section 734. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. In recent years, failures of reactor internal components have been observed after the components have reached neutron fluence levels 5 x 10 20 ncm2 e 1 mev. Transgranular, granulated, and intergranular stress. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Cracks were located mainly at positions close to the weld joint and the arc where very strong tensile residual stress existed. Pdf stress corrosion cracking of austenitic stainless.
Scoping stress corrosion cracking scc tests of 304 stainless steel ss were performed in 75 c and 250 c aerated pressurized water apw and 250 c deaerated pressurized water dpw. To understand the corrosion resistance properties of duplex stainless steel, you must also understand the concept of stress corrosion cracking. Stress corrosion cracking resistance is superior to the austenitic grades of stainless steel. Their mixed microstructure provides improved resistance to chloride stress corrosion cracking in comparison to austenitic stainless steel types 304 and 316. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. A great concern for the longterm integrity of canisters located near the coastline is chlorideinduced stress corrosion cracking of austenitic stainless steels 3,4,5. The type 302, 304, 304l and 305 alloys are the most susceptible of the austenitic stainless steels to stress corrosion cracking in halides because of their relatively low nickel content. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. The lower carbon content minimizes chromium carbide precipitation due to welding and its susceptibility to intergranular corrosion. Many times a good starting point is type 304 stainless because it is the most widely used stainless grade for increased corrosion resistance, move up to type 316 stainless, and for.
Stress corrosion cracking susceptibility of 304l substrate. Corrosion behaviour of type 316l stainless steel in hot. Stress corrosion cracking facts and how to reduce the risk. The effect of alloying elements and how these elements affect the electrochemical response in 50% naoh environments can be assessed, by comparing individual alloy responses. Ae signals came from ligament tearing and plastic deformation of crack. Galvanic corrosion stress corrosion cracking factors affecting corrosion corrosion testing. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. Unexpected corrosion of stainless steel in high solids black. Type 304 is the most versatile and widely used stainless steel. The stress corrosion cracking scc of aisi 304 and aisi 316 austenitic stainless steels in 0. Examples of chlorideinduced scc have been reported on the surfaces of type 304, 304l, and 316l stainless steel components in chemical reactor vessels, urea plant vessels, rock climbing equipment, and at nuclear power plants. Grade 304 stainless steel is excellent in a wide range of atmospheric environments and many corrosive media. Stainless steel characteristics eagle stainless your. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and.
Pitting corrosion has been reported from household bleach spills on stainless steel 304 type sinks in domestic environments. Specifications type 444 stainless steel sheet and strip is covered by the following. Stress corrosion cracking of a 304 stainless steel elbow. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenancefree service life of the structure. All three families of the highperformance stainless steels will deliver a wide range of resistance to chloride pitting and stress corrosion cracking superior to that of types 304 and 316.
Sensor requirements for detection and characterization of. Potential and strain rate effects in slow strain rate stress. Burst and continuous ae signals were detected during scc in hightemperature water. Chloride stress corrosion cracking in austenitic stainless. The 250 c apw environment was used to initiate intergranular stress corrosion cracking igscc and then the water. It is found that the stress vs timetofailure curves for both alloys are divided into three regions that are dominated by either stress.
Duplex grades are usually divided into three subgroups based on their corrosion resistance. The final, definitive version of this document can be found online at. Several chapters are spent on those special forms of corrosion that are investigated in the great detail in stainless steels, namely, pitting corrosion, crevice corrosion, and stress corrosion cracking. The most common type of 304 stainless steel is the 188 or 188 steel, which constitutes 18% chromium and 8% nickel. This research was focused on the failure analysis of a cracked ss304 stainless steel elbow from a chemical plant. The general pattern of the observed failures indicates that as nuclear plants age and fluence increases, various apparently nonsensitized. The higher nickel and molybdenum content in this grade allows it to demonstrate better overall corrosion resistant properties than 304, especially with regard to pitting and crevice corrosion. Scc in a 316 stainless steel chemical processing piping system. Because ss 304 contains 18% chromium cr and 8% nickel ni, its also known as 188 stainless steel.
Pitting resistance is also superior in comparison to types 304 and 316. Highlightstypical scc modes and different crack growth rates were designed. Stainless steels are more resistant to general corrosion compared with carbon steel. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. They have magnetic properties, too, offers good ductility, tensileproperty stability, and resistance to corrosion, thermal fatigue, and stress corrosion cracking. Practical solutions by solutions for people, processes and paper. Feb 15, 2017 aisi 304 stainless steel ss is one of the candidate materials used for dry storage canisters of spent nuclear fuel as an interim storage measure before final disposal 1,2. This results because of their similarity in nickel content. Irradiationinduced stress corrosion cracking of austenitic stainless steels. Usually ferritic stainless steel is immune to stress corrosion cracking. When steel is embrittled and fails by cracking due to exposure to hydrogen in the presence of stress, the failure. The influences of thermal treatment heat affected zone cases, composition, and microstructure on corrosion are given good coverage. Fatigue crack growth behavior of aisi 304 stainless steel plate and its plasma weld was evaluated in laboratory air and gaseous hydrogen. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0.
Austenitic stainless steels are however vulnerable to stress corrosion cracking scc in specific environmental conditions including when exposed to hydrogen. Effects of hydrogen charging on the stress corrosion cracking scc behavior of 304 and 310 stainless steels under sustained load were investigated in boiling 42% mgcl2 solution. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. High performance stainless steels nickel institute.
Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. The general level of corrosion resistance of ak steel 2205 duplex is superior to types 304 and 316 in most cases. Influence of high temperature on corrosion behavior of 304. Astm g123002015, standard test method for evaluating stress corrosion cracking of stainless alloys with different nickel content in boiling acidified sodium chloride solution, astm international, west conshohocken, pa, 2015. Their chemical composition, mechanical properties, weldability and corrosionoxidation resistance provide the best allround performance stainless. The low carbon version, 304l, may be required for full corrosion resistance when thicker sections are welded. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Corrosion resistance of stainless steels corrosion in concrete corrosion problems are not limited to outside surfaces. Grade 304 is the most commonly used stainless steel. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Hence the tendency for stress corrosion cracking of the plain 304 or 316 stainless steels in solution annealed condition is not considered to be different from its low carbon varieties.
And austenitic stainless steel is prone to low stress or residual stress corrosion cracking. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and carbonatebicarbonate solutions. Corrosion resistance stress corrosion cracking 2205 is a cost effective solution for many applications where 300 series stainless steels are susceptible to chloride stress corrosion cracking scc. May 18, 2005 corrosion resistance of stainless steel 304. There is an additional risk of stress corrosion cracking scc at higher temperatures. Chloride stress corrosion cracking although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless steels varies substantially. Type 304 stainless steel an overview sciencedirect topics.
Aisi 304 stainless steel ss is one of the candidate materials used for dry storage canisters of spent nuclear fuel as an interim storage measure before final disposal 1,2. Role of hydrogen in stress corrosion cracking of austenitic. Aisi 304l is the low carbon version of 304 stainless steel, aisi 316 is better than grade 304 in certain properties, corrosion resistance and heat resistance, etc. Astm g123 002015 standard test method for evaluating. Insitu monitoring of stress corrosion cracking of 304 stainless steel in hightemperature water by analyzing acoustic emission waveform. Reference is often made to stainless steel in the singular sense as if it were one material. Low temperature stress corrosion cracking of stainless steels in the atmosphere in presence of chloride deposits article in corrosion houston tx 652. Stress corrosion cracking facts and how to reduce the. The effect of cold work on the stresscorrosion cracking of. Transgranular stresscorrosion cracking is observed accompanied by pitting. Ferritic steels are the 400 grade stainless steels noted for their high chromium content, which can range from 10. The saeansi 304 aisi 304 is the most commonly available and used type of stainless steel. Unexpected corrosion of stainless steel in high solids black liquor service. It has excellent forming and welding characteristics.
For more information, please check 304 vs 316 stainless steel. Stress corrosion cracking of type 304 austenitic stainless. Not only can duplex stainless steel hold up reliably through trauma impact, but through corrosion as well. Ss304 grade aisi 304 stainless steel properties, composition. It is an austenitic, corrosion resistant steel with excellent strength, toughness, fabrication characteristics and weldability. Three general classifications are used to identify stainless steels. Current density time plots made during constant straining and fractographic observations show different types of crack formation. The potential for stress corrosion cracking scc of welded stainless steel interim storage containers for spent nuclear fuel snf has been identified as a high priority data gap.
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